Gmail in the browser is, in my experience, better than Skype. The voice and video chat worked flawlessly from San Francisco to the Philippines where under the exact same circumstances Skype stuttered and failed for video conferencing.
Also - Gmail in the browser is integrated with Google Voice and Google Chat, so you don't have to suffer through Skype's client just to chat. And in fact you can continue chatting over your phone through SMS (for free) because Google Voice is awesome.
Also, can someone please create a viable Skype alternative that actually works?